李志芳(研究员)的个人简介
李志芳,1975年1月生,1998年毕业于河南师范大学,2003年在浙江大学获理学博士学位。2003-2005年受日本学术振兴会资助,作为日本学术振兴会外国人特别研究员(JSPS)在大阪府立大学从事博士后研究工作。先后负者日本学术振兴会外国人特别研究员研究基金一项,作为主要完成人参与国家“863”计划项目一项、国家五部委重点项目一项、国家自然科学基金三项。作为第一作者,在国际期刊上发表研究论文30余篇。
工作和学习背景
现在主要从事有机硅、锗和锡化学,包括官能团化有机硅单体和光学活性聚硅烷合成,稳定的不饱和14-族有机金属化合物合成及其结构和它们的反应活性的研究。
2005、05-至今杭州师范大学有机硅化学及材料技术教育部重点实验室 2003/06 u2013 2005/06 大阪府立大学, 日本学术振兴会外国人特别研究员(JSPS),Ogawa实验室
1998/09-2003/04 浙江大学有机化学研究所有机化学专业,理学博士学位,
指导老师:张永敏 教授
1994/09-1998/06 河南师范大学化学系化学教育专业,学士学位
论文
2002年以来发表的主要研究论文 1. A New Entry to the Construction of Si-Si Linkage: Sm/SmI2-Induced Efficient Reductive Coupling of Organochlorosilanes
Zhifang Li, Koichiro Iida,Yuri Tomisaka, Aya Yoshimura, Toshikazu Hirao, Akihiro Nomoto, Akiya Ogawa, Organometallics, 2007, 26(5), 1212-1216.
2. FERRIC CHLORIDE-CATALYZED DEOXYGENATIVE CHLORINATION OF CARBONYL COMPOUNDS TO HALIDES,
Zhifang Li, Chunqi Sheng, Huayu Qiu and Yongmin Zhang, Org. Prep. Proc. Int. 2007, 39(4), 429-432.
3. Direct Construction of Silicon-Silicon Bond by Using the Low-Valent Titanium
Guoqiao Lai, Zhifang Li, Jiabang Huang, Jianxiong Jiang, Huayu Qiu, Yongjia Shen, J. Organomet. Chem. 2007, 692, 3559-3562.
4. Controlled Introduction of Allylic Group to Chlorosilanes
Zhifang Li, Xiaojun Cao, Guoqiao Lai, Jinhua Liu, Yong Ni, Jirong Wu, Huayu Qiu, J. Organomet. Chem. 2006, 691, 4740-4746.
5. A Highly Efficient Reduction of Group 14 Heteroatom-Chlorine Single Bonds by Using Samarium Diiodide-Mediated Reaction Systems
Ikuyo Kamiya, Koichiro Iida, Zhifang Li, Yuri Tomisaka, Akiya Ogawa, J. Alloys Comp. 2006, 408-412, 437-440
6. Reductive Dimerization and Polymerization of Organochlorosilanes Mediated by a Sm/SmI2 Mixed System
Zhifang Li, Yuri Tomisaka, Akiya Ogawa, International Symposium Rare Earthsu2019 04 in Nara, Japan, November 7-12, 2004.
7. Low-Valent Samarium Promoted Reductive Polymerization of Organochlorosilanes
Zhifang Li, Akiya Ogawa, Rare Earths, 2004, 45, 232.
8. Novel Cyclization of Dimeric Dianions of Anils or Aldehydes with Triphosgene: A Safe and Efficient Synthesis of Substituted Imidazolidin u20132-ones and 4,5-Diaryl-1,3-dioxolan u20132-ones
Zhifang Li and Yongmin Zhang, Heteroatom Chem. 2003, 14 (1) 46-49.
9. Direct construction of quaternary carbon center utilizing an allylsamarium bromide reagent
Zhifang Li and Yongmin Zhang, Tetrahedron 2002, 58 (26), 5301.
10. Direct Construction of Quaternary Carbon Centre Utilizing an Organosamarium Reagent
Zhifang Li and Yognmin Zhang , Tetrahedron Lett. 2002, 42, 8507.
11. Low-Valent Titanium Induced Cyclization of Dimeric Dianions of Anil with Triphosgene: A Safe and Efficient Method for the Synthesis of Substituted Imidazolidine
Zhifang Li and Yongmin Zhang, Synth. Commun. 2002, 32(17), 2613-2618.
国际会议论文
1. International Symposium Rare Earthu2019 04 in Nara, Japan,
Reductive Dimerization and Polymerization of Organochlorosilanes Mediated by a Sm/SmI2 Mixed System, Li Zhifang, and Ogawa Akiya
2. China, Korea and Japan Tri-National Symposium on Silicon,2006, 11. 13-15th
Direct Construction of Silicon-Silicon Bond by Using the Low-Valent Titanium, Li Zhifang and Quoqiao Lai
3. 1st Pacific Symposium on Radical Chemistry (PSRC-1), November 15-16, 2004, Kanazawa, Japan
Low-valent Rare Earth Promoted Reaction of Chlorosilanes Li Zhifang, and Ogawa Akiya
主持过的主要科研项目
1. Development of Photo-induced New Catalytic Systems of Rare Earth Complexes (编号P03091, 240万日元,日本学术振兴会,2003年6月 29---2005年6月28)。
2.稀土金属催化液晶聚硅烷的合成研究
杭州市留学人员科研活动择优资助项目 2万,2006年12月-2007年12月。
3.有机硅介孔负载催化剂的制备及其对硅氢加成反应的催化性能研究, 4万,2007,4-2009,3。